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Synlett 1991; 1991(9): 649-650
DOI: 10.1055/s-1991-20828
DOI: 10.1055/s-1991-20828
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Anionic Hetero[3,3] Rearrangements. N-Acylhydroxylamine-O-carbamates to α-Amino Acids: A New Method for Introduction of Amino Groups at the α-Position of Carboxylic Acids
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Publikationsdatum:
07. März 2002 (online)
N-Acylhydroxylamine-O-carbamates rearrange under basic conditions to afford α-amino acid amide derivatives. The rearrangement, which can be rationalized in terms of [3,3] sigmatropic shifts, is applicable to α-amination of carboxylic acids.