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Synlett 1991; 1991(11): 825-826
DOI: 10.1055/s-1991-20892
DOI: 10.1055/s-1991-20892
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Chemoselective Conjugate Reduction of α,β-Unsaturated Esters and Lactones Under Mild Conditions
Further Information
Publication History
Publication Date:
07 March 2002 (online)
Several pyranose-derived α,β-unsaturated lactones and esters undergo chemoselective conjugate reduction by a tandem benzenethiol addition-tributyltin hydride reduction, without isolation of the intermediates, to the corresponding carbonyl compounds in good yield. The method is compatible with the presence of various protecting groups.