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Synlett 1991; 1991(12): 871-872
DOI: 10.1055/s-1991-20907
DOI: 10.1055/s-1991-20907
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Synthesis of the C14-C27 Fragment of Tetronasin
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Publikationsverlauf
Publikationsdatum:
07. März 2002 (online)
![](https://www.thieme-connect.de/media/synlett/199112/lookinside/thumbnails/10.1055-s-1991-20907-1.jpg)
The pyranosyl unit 11 (2-formyl-6-[1,2-(isopropylidenedioxy)ethyl]-5-methyltetrahydropyran) of tetronasin was prepared from D-glyceraldehyde acetonide and a coupling reaction between 11 and the sulfone 13 (5-(1-methoxyethyl)-3-methyl-2-[1-methyl-2-(phenylsulfonyl)ethyl]tetrahydrofuran) of a tetrahydrofuranyl fragment gave the desired C14-C27 fragment of tetronasin.