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Synlett 1991; 1991(12): 919-920
DOI: 10.1055/s-1991-20923
DOI: 10.1055/s-1991-20923
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Novel Synthesis of 1-Cyanocyclopropane-1-carboxylic Acid and Its Application to the Synthesis of Amino Acids Containing Cyclopropane Rings
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Publikationsverlauf
Publikationsdatum:
07. März 2002 (online)
![](https://www.thieme-connect.de/media/synlett/199112/lookinside/thumbnails/10.1055-s-1991-20923-1.jpg)
1-Cyano-1-trimethylsilylcyclopropanes 1 were efficiently converted to 1-cyanocyclopropane-1-carboxylic acids (2) in the presence of a fluoride ion source under a carbon dioxide atmosphere. This transformation provides a novel route to 1-aminocyclopropane-1-carboxylic acid (ACC), which is found in many plants, and to its homolog 7 (1-aminomethylcyclopropane-1-carboxylic acid).