RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000083.xml
Synlett 1991; 1991(5): 335-336
DOI: 10.1055/s-1991-34727
DOI: 10.1055/s-1991-34727
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Acyl Radical Macrocyclisations. A Synthesis of the Furanocembrane Unit in Lophotoxin and Pukalide
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
07. März 2002 (online)
![](https://www.thieme-connect.de/media/synlett/199105/lookinside/thumbnails/10.1055-s-1991-34727-1.jpg)
A concise synthesis of the furanocembrane unit 5 (10-isopropenyl-3,7,13-trimethyl-15-oxabicyclo[10.2.1]pentadeca-2,6,12,14-tetraene) found in the neurotoxin lophotoxin 3 and the related pukalide 4 is described. The synthesis uses a tandem intramolecular cyclisation strategy and the novel acyl radical macrocyclisation 7 → 6, as key features.