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Synlett 1991; 1991(10): 699-701
DOI: 10.1055/s-1991-34762
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Glycosylation of 1,1,3,3-Tetraisopropyldisiloxane-1,3-diyl Protected Methyl GIucopyranosides Using 2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Fluoride

Thomas Ziegler* , Karin Neumann, Elisabeth Eckhardt, Gerhard Herold, Guido Pantkowski
  • *Institut für Organische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-7000 Stuttgart 80, Germany
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Publication Date:
13 March 2002 (online)

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1,1,3,3-Tetraisopropyldisiloxane-1,3-diyl protected methyl α-D-glucopyranosides were regioselectively glycosylated in good yield with 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl fluoride and diethyl ether-boron trifluoride as the catalyst.