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Synlett 1991; 1991(10): 741-742
DOI: 10.1055/s-1991-34764
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Microbial Oxidation in Synthesis: Preparation of Novel 3-Substituted cis-Cyclohexa-3,5-diene-1,2-diol Derivatives from (1S,2S)-3-Bromocyclohexa-3,5-diene-1,2-diol

Steven V. Ley* , Alison J. Redgrave, Stephen C. Taylor, Safia Ahmed, Douglas W. Ribbons
  • *Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, England
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Publication Date:
13 March 2002 (online)

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A range of 3-substituted cis-cyclohexa-3,5-diene-1,2-diol derivatives (silyl, stannyl, aryl, alkenyl and alkynyl) have been prepared from the acetonide of readily available (1S,2S)-3-bromocyclohexa-3,5-diene-1,2-diol (1) under palladium-catalysed cross-coupling conditions.