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Synlett 1992; 1992(4): 269-271
DOI: 10.1055/s-1992-21335
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A Stereocontrolled Approach to the Oxa-Bridged Octalin System of Coloradocin (Luminamicin)

Jeffrey M. Evans* , James Kallmerten
  • *Department of Chemistry, Syracuse University, Syracuse, New York 13244-4100, USA
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Publication Date:
08 March 2002 (online)

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The 5-methylene-1,2,3,4,4a,5,8,8a-octahydronaphthalen-2-ol 17 undergoes intramolecular cyclization to provide an entry into the 11-oxatricyclo[5.3.1.03,8]undec-5-ene system of coloradocin (1).