PDF herunterladen
Synlett 1992; 1992(6): 521-523
DOI: 10.1055/s-1992-21401
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Domino-Heck Coupling of Aryl Halides and Dicyclopentadiene: A Simple Access to Polycyclic Arene-Anellated Cyclopentadienes as Ligands for Metal Complexes

Karsten Albrecht* , Oliver Reiser, Martin Weber, Armin de Meijere
  • *Institut für Organische Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, D-3400 Göttingen, Germany
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
08. März 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Domino coupling products of haloarenes and norbornene as well as dicyclopentadiene can be converted to polycyclic aromatic compounds like benzo[e]pyrene (3), benzo[e]cyclopenta[I]pyrene (4), 7-phenyl-1H-cyclopenta[I]phenanthrene (10) and 1H-cyclopenta[f][3,8]phenanthroline (16). Compounds 4 and 10 can serve as new ligands in metal complexes such as ferrocenes 17, 18a and titanocene 18b.