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Synlett 1992; 1992(8): 665-667
DOI: 10.1055/s-1992-21451
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Titanium-Mediated Carbonyl Olefinations; 3: Conversion of Carbonyl Compounds to Vinylsilanes with Cyclopentadienyl(trimethylsilylmethyl)titanium(IV) Derivatives

Nicos A. Petasis* , Irini Akritopoulou
  • *Department of Chemistry, University of Southern California, Los Angeles, California 90089-0744, USA
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Publication Date:
08 March 2002 (online)

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A variety of carbonyl derivatives are converted to vinylsilane products upon heating with bis(trimethylsilylmethyl)titanocene or cyclopentadienyl[tris(trimethylsilylmethyl)]titanium(IV).