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Synlett 1993; 1993(2): 165-167
DOI: 10.1055/s-1993-22390
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Expeditious Syntheses of α- and β-(1→6-Linked C-Disacćharides by way of SRN1 Coupling Processes

Olivier R. Martin* , Fang Xie, Ramesh Kakarla, Rachid Benhamza
  • *Department of Chemistry, Binghamton University, State University of New York, P.O. Box 6000, Binghamton, New York 13902-6000, USA
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Publication Date:
19 March 2002 (online)

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The photolytically-induced cross-coupling of α- and β-glycosylmethyl radicals, generated from the corresponding cobaloximes, with nitronate ions derived from 6-nitro sugars, provides an expeditious approach to α- and β-(1→6)-linked C-disaccharides.