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Synlett 1993; 1993(3): 223-226
DOI: 10.1055/s-1993-22411
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Synthesis of Functionalized Cyclophanes via a Self-Templating Effect

Andrew C. Benniston* , Anthony Harriman
  • *Center for Fast Kinetics Research, The University of Texas at Austin, Austin, Texas 78712, USA
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Publikationsdatum:
19. März 2002 (online)

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A functionalized cyclophane has been synthesized in a one-pot coupling reaction which forms extremely stable chargetransfer complexes with added donors. A key feature of the final coupling step involves formation of a zwitterionic open chain molecule which is appropriately oriented for cyclization.