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Synlett 1993; 1993(8): 548-550
DOI: 10.1055/s-1993-22523
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Stereospecific Synthesis of cis- and trans-Galbanolenes by Na(Hg) Reductive Elimination of Allylic Dibenzoates

Guy Solladie* , Antonio Urbano, Guy B. Stone
  • *Ecole Européenne des Hautes Etudes des Industries Chimiques de Strasbourg (EHICS), Laboratoire de Stéréochimie Associé au CNRS, 1, rue Blaise Pascal, F-67008 Strasbourg, France
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Publication Date:
19 March 2002 (online)

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A stereospecific and high yielding synthesis of cis- and trans-Galbanolenes is described utilizing a novel triene synthesis, the Na(Hg) reductive elimination of 1,6-dibenzoate-2,4-dienes and 1,4-dibenzoate-2-alkenes.