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Synlett 1993; 1993(9): 689-690
DOI: 10.1055/s-1993-22573
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Copper-Catalyzed SN2′-Selective Cross Coupling Reaction Between Grignard Reagents and Allylic Phosphates

Akira Yanagisawa* , Nobuyoshi Nomura, Hisashi Yamamoto
  • *School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan
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Publication Date:
19 March 2002 (online)

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The SN2′-selective Grignard coupling with primary allylic diphenylphosphates was successfully achieved in the presence of a catalytic amount of CuCN·2LiCl. γ-Substituted allyl Grignard reagents reacted with allylic phosphates selectively at the less substituted allylic terminus.