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Synlett 1993; 1993(12): 895-896
DOI: 10.1055/s-1993-22642
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A Simple Enantioselective Synthesis of (-)-S- and (+)-R-Camphonanic Acids

Antonio Abad* , Consuelo Agulló, Manuel Arnó, Ana C. Cuñat, Ramón J. Zaragozá
  • *Departamento de Química Orgánica, Facultad de Químicas, Universitad de Valencia, C/ Dr. Moliner 50, E-46100 Burjassot, Valencia, Spain
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Publikationsdatum:
19. März 2002 (online)

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A four step enantioselective synthesis of 1S- and 1R-1,2, 2-trimethylcyclopentanecarboxylic acids [(S)- and (R)-camphonanic acid, (-)-1 and (+)-1 respectively] has been achieved from ß-cyclogeraniol, using a Katsuki-Sharpless asymmetric epoxidation and a pinacollic rearrangement as key synthetic steps.