Diastereoselective Alkylations with η2-Manganese Complexes

Dieter Schinzer; Thorsten Blume; Roy Uwe Rojas Wahl

doi:10.1055/s-1994-22836

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Synlett 1994; 1994(4): 297-298
DOI: 10.1055/s-1994-22836

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Diastereoselective Alkylations with η²-Manganese Complexes

Dieter Schinzer^* , Thorsten Blume, Roy Uwe Rojas Wahl

^*Institut für Organische Chemie der Technischen Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany

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Publication Date:
22 March 2002 (online)

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Manganese η²-complexes of enones (cyclohexenone and cyclopentenone) have been prepared and their alkylations were studied. Only the alkylations of the η²-complexes of manganese with cyclopentenone yielded diastereoselectively the desired exo-products of type 6.