Diastereoselective C,C Bond Formations with η2-Manganese Complexes: Aldol Reactions

Dieter Schinzer; Thorsten Blume; Michael Woltering

doi:10.1055/s-1994-23080

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Synlett 1994; 1994(12): 1045-1046
DOI: 10.1055/s-1994-23080

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Diastereoselective C,C Bond Formations with η²-Manganese Complexes: Aldol Reactions

Dieter Schinzer^* , Thorsten Blume, Michael Woltering

^*Institut für Organische Chemie der Technischen Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany

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Publication Date:
22 March 2002 (online)

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Manganese η²-complexes of cyclopentenone have been prepared and their aldol reactions studied. Enolates of η²-complexes of manganese yielded with various aldehydes the desired anti-aldol products of type 3 diastereoselectively.