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Synlett 1994; 1994(12): 1045-1046
DOI: 10.1055/s-1994-23080
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Diastereoselective C,C Bond Formations with η2-Manganese Complexes: Aldol Reactions

Dieter Schinzer* , Thorsten Blume, Michael Woltering
  • *Institut für Organische Chemie der Technischen Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany
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Publikationsdatum:
22. März 2002 (online)

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Manganese η2-complexes of cyclopentenone have been prepared and their aldol reactions studied. Enolates of η2-complexes of manganese yielded with various aldehydes the desired anti-aldol products of type 3 diastereoselectively.