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Synlett 1995; 1995(1): 101-102
DOI: 10.1055/s-1995-4844
DOI: 10.1055/s-1995-4844
letter
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Synthesis of Bridged Bicyclic β-Trifluoroacetoxy β-Trifluoromethyl α-Amino Acid Derivatives by an Original Dakin-West/Diels-Alder Tandem Sequence
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199501/lookinside/thumbnails/10.1055-s-1995-4844-1.jpg)
The reaction of hippuric acid with trifluoroacetic anhydride in the presence of cyclopentadiene affords useful bicyclic α-amino acid derivatives bearing β-trifluoroacetoxy and β-trifluoromethyl groups.
β-trifluoromethyl α-amino acids - Diels-Alder cycloaddition - Dakin-West reaction - 2-phenyl-5-oxazolone - tandem sequence