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Synlett 1995; 1995(1): 103-104
DOI: 10.1055/s-1995-4849
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Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation

Jonathan Clayden, Marc Julia*
  • *Laboratoire de Chimie de l’Ecole Normale Supérieure, 24 rue Lhomond, 75231 Paris Cedex 05, France
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Publikationsdatum:
31. Dezember 2000 (online)

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3-Chloroalkyl ethers can be deprotonated α to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecularly to give α-halosilanes or cyclopropanes.

carbenoid - metallation - LiC-KOR reagent - α-halosilane - cyclopropane