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Synlett 1995; 1995(1): 81-82
DOI: 10.1055/s-1995-4857
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Aluminum Tris(2,6-diphenylphenoxide) (ATPH) as an Efficient and Selective Activator for Inoue Polymerization

Keiji Maruoka, Matsujiro Akakura, Hisashi Yamamoto*
  • *School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan
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Publication Date:
31 December 2000 (online)

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Visible, light-induced, high speed polymerization of alkyl methacrylate catalyzed by aluminum porphyrin gives a polymer with sharp molecular weight distribution in the presence of aluminum tris(2,6-diphenylphenoxide) as an efficient and selective activator of methacrylate carbonyls.

aluminum tris(2,6-diphenylphenoxide) - polymerization - aluminum porphyrins - methyl methacrylate