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Synlett 1995; 1995(4): 319-320
DOI: 10.1055/s-1995-4962
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Model Studies Related to Classical Synthetic Approaches to [60]-Fullerene and its Siblings

Goverdhan Mehta* , K. Venkateswara Rao
  • *School of Chemistry, University of Hyderabad, Hyderabad 500 134, India; Jawaharlal Nehru Center for Advanced Scientific Research, Bangalore 560 012, India
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Publication Date:
31 December 2000 (online)

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A short, flexible approach is conceived towards [60]-fullerene 1 employing photochemical and thermal cyclization as pivotal steps and access to a C35-hydrocarbon constituting a segment of 1 is reported.

C60-fullerene - bowl-shaped fullerene fragments - Barbier reaction - photocyclisation - Pd/C Cyclodehydrogenation