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Synlett 1995; 1995(4): 336-338
DOI: 10.1055/s-1995-4975
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CsF in Organic Synthesis. A Practical Method for Inversion of Secondary Mesylates

Tsuneo Sato, Junzo Otera*
  • *Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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The virtually perfect inversion of secondary mesylates by a variety of nucleophiles is effected through promotion by CsF in DMF.

inversion - SN2 - CsF - mesylate