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Synlett 1995; 1995(6): 645-646
DOI: 10.1055/s-1995-5042
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Umpolung Addition Reaction of Nucleophiles to 2,3-Butadienoates Catalyzed by a Phosphine

Chunming Zhang, Xiyan Lu*
  • *Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China, Fax: 86-21-4166128
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Publikationsdatum:
31. Dezember 2000 (online)

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Addition of carbon and oxygen nucleophiles to 2,3-butadienoates under the catalysis of a phosphine gave inverse addition products regioselectively. The mechanism is briefly discussed.

nucleophile - 2,3-butadienoates - phosphine-catalyzed - umpolung - inverse addition