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Synlett 1995; 1995(SI): 547-548
DOI: 10.1055/s-1995-5266
DOI: 10.1055/s-1995-5266
letter
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Synthetic Studies on Pancratistatin. Construction of the Phenanthridone Ring System via a Hydrogen Bond Controlled Enamide Photocyclization
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/1995SupI/lookinside/thumbnails/10.1055-s-1995-5266-1.jpg)
Synthesis of the phenanthridone core of the antineoplastic alkaloid pancratistatin is reported. The key step is a regiocontrolled aryl enamide photocyclization that produces the trans-BC ring fusion characteristic of the natural product.
pancratistatin - phenanthridone - enamide - photocyclization - hydrogen-bonding