Tandem Radical Cyclisation Reactions for the Construction of Pseudocopsinine and Aspidosperma alkaloid models

Philip J. Parsons; Clive S. Penkett; Michael C. Cramp; Robert I. West; John Warrington; Marcelo C. Saraiva

doi:10.1055/s-1995-5278

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Synlett 1995; 1995(SI): 507-509
DOI: 10.1055/s-1995-5278

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Tandem Radical Cyclisation Reactions for the Construction of Pseudocopsinine and Aspidosperma alkaloid models

Philip J. Parsons^* , Clive S. Penkett, Michael C. Cramp, Robert I. West, John Warrington, Marcelo C. Saraiva

^*Department of Chemistry, University of Reading, Whiteknights, Reading, Berks. RG6 2AD, England

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Publication Date:
31 December 2000 (online)

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A very simple and potentially valuable synthetic approach to indole alkaloids is described which utilises a 3+2 nitrone cycloaddition¹ followed by a tandem radical cyclisation².

Cyclisation - radical - alkaloid