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Synthesis 1996; 1996(10): 1203-1206
DOI: 10.1055/s-1996-4371
DOI: 10.1055/s-1996-4371
paper
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The Oxidation of (Arene)tricarbonylchromium Alcohols
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synthesis/199610/lookinside/thumbnails/10.1055-s-1996-4371-1.jpg)
(Arene)tricarbonylchromium alcohols are oxidized to aldehydes or ketones by either DMSO-TFAA (trifluoroacetic anhydride) or DMSO-SO3-pyridine reagents, with minimal complication from decomplexation or methylthiomethyl ether formation. Both benzylic and non-benzylic alcohols may be oxidized successfully, with a kinetic preference for the former.
(arene)tricarbonylchromium alcohols - oxidation - activated DMSO reagents