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Synlett 1996; 1996(6): 585-586
DOI: 10.1055/s-1996-5487
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Stereocontrolled Synthesis of syn and anti N-Protected 3-Amino-2-Hydroxy Alkanoic Esters from Aminoalkyl Epoxides

L. Pégorier, M. Haddad, M. Larchevêque*
  • *Laboratoire de Synthèse Organique associé au CNRS, ENSCP, 11 rue Pierre et Marie Curie, 75231 - Paris Cedex 05, France, Fax 33 143 257975
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Publikationsdatum:
31. Dezember 2000 (online)

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Syn or anti N-protected 3-amino-2-hydroxyalkanoic esters were synthesized from anti aminoalkyl epoxides by intra or intermolecular reaction with O-nucleophiles and RuCl3-NaIO4 oxidation of intermediate primary alcohols.

Epoxyketone - epoxyamine - stereoselective epoxide ring opening