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Synlett 1996; 1996(8): 764-766
DOI: 10.1055/s-1996-5526
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Synthesis of Intermediates for the Elaboration of Glycosylphosphatidylinositol (GPI) Analogues

Maria Mirtes Silva, Jeannine Cleophax1 , Aloisio A. Benicio, Mauro V. Almeida, Jeanne-Marie Delaumeny, Antonio S. Machado2 , Stephan D. Gero
  • 1Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif/Yvette Cedex France
  • 2Departamento de Química, ICEx UFJF 36036.040, Juiz de Fora, M.G Brazil
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Publication History

Publication Date:
31 December 2000 (online)

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Protected D-3-O-(2’-amino-2’-deoxy-α-D-gluco-pyranosyl)-5-deoxy-chiro-inositol 6-phosphate 12 and the epoxide 13 were synthesized by glycosylation of a D-5-deoxy-chiro-inositol 6-phosphate 4 using Ferrier acid-catalysed rearrangement on 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-D-glucal 6.

Phosphoinositides - 2-deoxy-2-phthalimido-D-glucal - Ferrier glycosylation