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Synlett 1996; 1996(9): 909-910
DOI: 10.1055/s-1996-5590
DOI: 10.1055/s-1996-5590
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
A Short Enantioselective Access to Pumiliotoxin 251D from L-Proline
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
The indolizidine framework of pumiliotoxin 251D having the appropriate functionalities for incorporation of the tertiary hydroxyl group at the C-8 and the 2-alkylidene side chain at C-6 has been achieved from L-proline using a 6-exo-dig radical cyclisation.
Pumiliotoxin 251D - L-proline - radical cyclisation