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Synlett 1996; 1996(9): 893-894
DOI: 10.1055/s-1996-5608
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A Novel, Stereocontrolled Synthesis of 1,2-trans-Cyclopropanes: Cyclopropyl Boronate Esters as Partners in Suzuki Couplings with Aryl Halides

Jens P. Hildebrand, Stephen P. Marsden*
  • *Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, e-mail: s.marsden@ic.ac.uk
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Publikationsdatum:
31. Dezember 2000 (online)

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A novel, stereospecific synthesis of 1,2-trans-disubstituted cyclopropanes is described, based upon the palladium (0) mediated cross-coupling of cyclopropyl boronic esters with aryl halides. This work forms the basis of a proposed new asymmetric synthesis of cyclopropanes.

cyclopropane - palladium - Suzuki - cyclopropyl boronate