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Synlett 1996; 1996(11): 1123-1124
DOI: 10.1055/s-1996-5678
DOI: 10.1055/s-1996-5678
letter
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A Novel and Facile Synthesis of 1,3,2-λ5-Dioxaphospholanes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)

A new synthesis of 1,3,2-λ5-dioxaphospholanes 1 was realised by direct reaction of dibromotriphenylphosphorane with primary, secondary alcohols, cyclic alcohols and pyrocatechol in near quantitative yield.
1,3,2-λ5-dioxaphospholane - dibromotriphenylphosphorane - vicinal diol - transphosphoranylation