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Synlett 1996; 1996(11): 1039-1040
DOI: 10.1055/s-1996-5679
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Direct Routes to 5,15-Diaryl-10,20-Diethynyl Porphyrins from Pyrrole

G. Scott Wilson, Harry L. Anderson*
  • *Dyson Perrins Laboratory, The University of Oxford, South Parks Road, Oxford OX1 3QY, Fax +44 (0) 1865 275674, e-mail Harry.Anderson@dyson.ox.ac.uk
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Publikationsdatum:
31. Dezember 2000 (online)

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5,15-bis(trimethylsilylethynyl)-10,20-diaryl porphyrins can be synthesised from pyrrole in two steps either by reaction of meso-(trimethylsilylethynyl)dipyrromethanes with benzaldehydes or by reaction of meso-aryldipyrromethanes with trimethylsilylpropynal; the latter route is more efficient.

pyrrole - dipyrromethane - porphyrin - acetylene - trimethylsilylpropynal