Download PDF
Synlett 1997; 1997(11): 1309-1311
DOI: 10.1055/s-1997-1011
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Allylation of Aldehydes with Allyltin Compounds in Acidic Aqueous Media-A Catalytic Version

Akira Yanagisawa, Miwa Morodome, Hiroshi Nakashima, Hisashi Yamamoto*
  • *Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Allylation reaction of aldehydes with allyltributyltin was achieved using Sn catalysts in acidic aqueous media. Exclusive aldehyde selectivity was observed for competitive reactions of aldehydes and ketones with allyltributyltin in the presence of 5 mol% of tetraallyltin or SnCl4 in a mixture of aqueous HCl solution and THF.

catalytic allylation - allyltributyltin - aldehyde - Sn catalyst - acidic aqueous media