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Synlett 1997; 1997(5): 632-634
DOI: 10.1055/s-1997-3214
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Asymmetric Tandem Reaction: Beckmann Rearrangements/ Allylsilane Cyclizations: Approach to the Optically Active Cephalotaxine-Framework

Dieter Schinzer1 , Ulrich Abel2 , Peter G. Jones3
  • 1Institut für Organische Chemie der Technischen Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany; Telefax: Int. +531/391-5386, E-mail: D.Schinzer@tu-bs.de; new address: Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, D-39106 Magdeburg, Germany, Telefax: Int. +391/67-12223, E-mail: Dieter.Schinzer@uni-magdeburg.de
  • 2Institut für Organische Chemie der Technischen Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany
  • 3Institut für Analytische und Anorganische Chemie der Technischen Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany
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Publikationsdatum:
31. Dezember 2000 (online)

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In connection with our studies of tandem reactions we report an symmetric route to benzazepane frameworks via planar chiral η6-chromium arene complexes.

Tandem reaction - asymmetric synthesis - η6-chromium arene complexes - allyl silanes - N-heterocyclic systems