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Synlett 1997; 1997(7): 812-814
DOI: 10.1055/s-1997-5783
DOI: 10.1055/s-1997-5783
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Conversion of α-Anilino Alkenenitriles to Amides by Chemoselective Palladium-Catalyzed Arylations
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Publikationsdatum:
31. Dezember 2000 (online)
The reactions of α-anilino alkenenitriles with iodobenzene catalyzed by palladium gave amides and benzonitrile. A general mechanism is proposed to explain the chemoselective arylation at the cyano group.
chemoselective - palladium-catalyzed - Heck reaction - arylation - α-anilino alkenenitriles