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Synlett 1997; 1997(1): 35-37
DOI: 10.1055/s-1997-682
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Allylsilane Terminated Domino Heck Reaction

Lutz F. Tietze* , Katja Heitmann, Thomas Raschke
  • *Institut für Organische Chemie der Georg-August-Universität Göttingen, Tammannstr. 2, D-37077 Göttingen (Germany), Fax: Int. 49(0)551 39-9476
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Publication Date:
22 March 2004 (online)

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The allylsilane terminated domino Heck reaction of the enynes 4, 5, 6 and 7 to give the hitherto unknown polycyclic indanes 8, 9, 10 and 11 are described. The reactions proceed in a regio- and stereoselective way with good yields allowing the efficient formation of substituted tricyclic compounds from monocyclic substrates by forming two cyclopentane moieties in one step and thus, showing again the usefulness of applying an allylsilane moiety as the terminating group in the Heck reaction.

Heck reaction - domino reaction - palladium - allylsilanes - indanes