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Synlett 1997; 1997(1): 47-50
DOI: 10.1055/s-1997-701
DOI: 10.1055/s-1997-701
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Novel Crown Ether Assemblies: The Role of Isobenzofurans for Attaching Crown Ethers to Rigid Molecular Racks in a Geometrically Precise Fashion
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Publikationsverlauf
Publikationsdatum:
22. März 2004 (online)
Rigid polyalicyclic nanostructures with extended and U-shaped geometry and functionalised with 15-crown-5 rings have been prepared from molrac mono or bisalkenes and new crown ether isobenzofurans; substituents in the 1,3-position of the isobenzofuran are used to modify stereospecifities in the cycloaddition process thereby acting as geometrical control agents in the construction process.
isobenzofurans - cycloaddition - nanostructures - 15-crown-5 - cavity structures