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Synlett 1997; 1997(2): 223-224
DOI: 10.1055/s-1997-728
DOI: 10.1055/s-1997-728
letter
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Condensation of Dimethyl-3-methylglutaconate with Aminoaldehydes: A Diastereoselective Synthesis of 5,6-Dihydro-(2H)-pyran-2-ones
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Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199702/lookinside/thumbnails/10.1055-s-1997-728-1.jpg)
Dimethyl-3-methylglutaconate reacts with chiral α-aminoaldehydes under basic conditions to afford substituted 5,6-dihydro-(2H)-pyran-2-ones. The anti derivatives were obtained in a diastereoselective manner.
aldolisation - aminoaldehydes - dimethyl-3-methylglutaconate - 5,6-dihydro-(2H)-pyran-2-ones - diastereoselectivity