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Synlett 1997; 1997(2): 175-176
DOI: 10.1055/s-1997-747
DOI: 10.1055/s-1997-747
letter
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Selective Formation of Mono- and Tetra-Cycloadducts by the Diels-Alder Reaction of [60]fullerene with 2,5-Dimethylthiophene S-Oxides
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199702/lookinside/thumbnails/10.1055-s-1997-747-1.jpg)
2,5-Dimethylthiophene S-monoxide and S,S-dioxide prepared from the corresponding thiophene by BF3-Et2O catalyzed oxidation with m-CPBA reacted with fullerene C60 at room temperature to produce specifically mono- and tetra-adduct respectively.
thiophene S-oxides - Diels-Alder reaction - [60]fullerene