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Synlett 1997; 1997(4): 371-372
DOI: 10.1055/s-1997-799
DOI: 10.1055/s-1997-799
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Diisopropoxyaluminium Trifluoroacetate: A New off the Shelf Metal Alkoxide Type Reducing Agent for Reduction of Aldehydes and Ketones
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199704/lookinside/thumbnails/10.1055-s-1997-799-1.jpg)
A new off the shelf reducing agent, diisopropoxyaluminium trifluoroacetate, has been prepared by reacting aluminium isopropoxide with trifluoroacetic acid in dichloromethane. It is a white solid and stable when stored under dry conditions. Using this reagent various aldehydes and ketones have been reduced to the corresponding alcohols in moderate to quantitative yields, at room temperature in short time.
reduction - aluminium alkoxides - trifluoroacetic acid - aldehydes - ketones