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Synlett 1997; 1997(8): 965-967
DOI: 10.1055/s-1997-957
DOI: 10.1055/s-1997-957
letter
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Stereospecific Syntheses of Michellamines A and C
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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The total syntheses of two of the three dimeric naphthylisoquinoline michellamines - A and C - were achieved by Pd-catalyzed cross-coupling of the appropriate 6'-bromo- or 6'-boronic acid-substituted tetrabenzylated korupsensamine A and B derivatives under nonaqueous conditions, followed by deprotection of the octabenzylated products.
naphthylisoquinoline alkaloids - michellamines - korupensamines - atropdiasteromer - Suzuki hetero-biaryl coupling