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Synlett 1998; 1998(2): 161-162
DOI: 10.1055/s-1998-1590
DOI: 10.1055/s-1998-1590
letter
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Suzuki Reactions with B-Allyl-9-Borabicyclo[3.3.1]nonane (B-Allyl-9-BBN)
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
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The mixture of borate complexes formed on treatment of B-allyl-9-BBN with KOMe readily undergoes Suzuki reactions in the presence of catalytic amounts of Pd(0) complexes, thus transferring their allyl moiety to aryl bromides, -iodides or -triflates.
allylation - cross coupling - Suzuki reaction - 9-BBN - palladium