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Synlett 1998; 1998(2): 161-162
DOI: 10.1055/s-1998-1590
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Suzuki Reactions with B-Allyl-9-Borabicyclo[3.3.1]nonane (B-Allyl-9-BBN)

Alois Fürstner* , Günter Seidel
  • *Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim/Ruhr, Germany; Fax +49-2 08-3 06-29 80; E-mail: fuerstner@mpi-muelheim.mpg.de
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Publication History

Publication Date:
31 December 2000 (online)

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The mixture of borate complexes formed on treatment of B-allyl-9-BBN with KOMe readily undergoes Suzuki reactions in the presence of catalytic amounts of Pd(0) complexes, thus transferring their allyl moiety to aryl bromides, -iodides or -triflates.

allylation - cross coupling - Suzuki reaction - 9-BBN - palladium