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Synlett 1998; 1998(2): 166-168
DOI: 10.1055/s-1998-1591
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Ruthenium-Catalyzed Yne-Ene Cross Metathesis Binding to Solid Support and Cleavage by Pd0-Catalysis

Stephan C. Schürer* , Siegfried Blechert
  • *Institut für Organische Chemie, Sekr. C3, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany; Fax +44 30/31 42 36 19; E-mail: sibl@wap0105.chem.tu-berlin.de
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Publikationsdatum:
31. Dezember 2000 (online)

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The solid phase synthesis of 1,3-dienes by yne-ene cross-metathesis involving binding of terminal alkenes to polystyrene resins, which contain propargyl ester groups, and their cleavage by Pd0-catalysis under C,C- or C,N-bond formation or reduction is demonstrated.

metathesis - catalytic immobilization - 1,3-dienes - combinatorial chemistry - Pd-catalysis