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Synlett 1998; 1998(7): 780-782
DOI: 10.1055/s-1998-1763
DOI: 10.1055/s-1998-1763
letter
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1,3-Stereoinduction in Radical Additions to Glyoxylate Imines
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
Addition of alkyl radicals to the acyclic glyoxylate imine 1 proceeded with a 70 : 30 stereoinduction, even at -78 °C. Addition to the cyclic imine 4b resulted in complete stereocontrol at -40 °C.
glyoxylate imines - stereoinduction - radical addition - α-aminoesters