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Synlett 1998; 1998(8): 921-923
DOI: 10.1055/s-1998-1814
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One-Pot Synthesis of Piperidines from Imines Using 3-Stannyl-2-(silylmethyl)propene

Kyung-Tae Kang* , Eon Hee Kim, Won Jeon Kim, Nam Sun Song, Jin Kyu Shin, Bo Young Cho
  • *Department of Chemistry, Pusan National University, Pusan 609-735, Korea; Fax + 82(51)516-7421; E-mail: kytkang@hyowon.cc.pusan.ac.kr
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Publikationsdatum:
31. Dezember 2000 (online)

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Various 2,6-disubstituted 4-methylenepiperidines were prepared in one-pot by the reactions of chlorotrimethylsilane or boron trifluoride activated aldimines with 3-tributylstannyl-2-(trimethylsilylmethyl)propene, and then with aldehydes.

allylstannane - allylsilane - 3-tributylstannyl-2-(trimethylsilylmethyl)propene - aldimine - piperidine