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Synlett 1998; 1998(8): 841-842
DOI: 10.1055/s-1998-1820
DOI: 10.1055/s-1998-1820
letter
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Stereoselective Reaction with Configurationally Stable α-Phenylthioalkylsamarium Compounds
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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α-Phenylthioalkylsamarium, prepared by a treatment of 1-chloroethyl phenyl sulfide with SmI2 in THF, reacted with aldehydes to give β-phenylthioalkanols with high diastereoselectivities; the configurational stability of the samarium reagents was also observed in their reaction with a chiral aldehyde.
lanthanides - samarium - stereoselective - enantiomerization - sulfur