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Synlett 1998; 1998(9): 967-968
DOI: 10.1055/s-1998-1838
DOI: 10.1055/s-1998-1838
letter
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SmI2-Mediated Reduction of α-Functionalised Amides: Highly Enantiospecific Access to an Atropisomeric Amide
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199809/lookinside/thumbnails/10.1055-s-1998-1838-1.jpg)
SmI2 or SmI2-LiCl mixtures can be used to reduce α-functionalised amides in yields of up to 85% depending upon the amide structure. The method has been applied to the synthesis of an atropisomeric anilide system in highly enantioenriched form, starting with (S)-O-acetyl lactic acid.
samarium iodide - reduction - amide - atropisomer