Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml
Synlett 1998; 1998(1): 53-54
DOI: 10.1055/s-1998-3124
DOI: 10.1055/s-1998-3124
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Enantioselective Allylic Substitution Using a Novel (Phosphino-α-d-glucopyrano-oxazoline)palladium Catalyst
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199801/lookinside/thumbnails/10.1055-s-1998-3124-1.jpg)
A novel enantiomerically pure 2-[2-(diphenylphosphino)phenyl]-4,5-(2-deoxy-α-d-glucopyrano)-oxazoline ligand (6) was prepared from glucosamine (1). The stereodifferentiating potential of the ligand 6 was demonstrated in palladium-catalyzed intermolecular allylic substitutions of symmetrically and non-symmetrically substituted allyl acetates which give products in high yields and high enantioselectivity (up to 98% ee).
enantioselective catalysis - palladium-catalyzed allylation - P,N-ligand - carbohydrate-derived ligand - glucosamine