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Synlett 2000; 2000(1): 149-151
DOI: 10.1055/s-2000-6457
DOI: 10.1055/s-2000-6457
letter
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Enhanced Stereoselectivity in the Catalytic Dihydroxylation of Acyclic Allylic Alcohols
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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A series of acyclic allylic alcohols were oxidised with catalytic osmium tetroxide. Use of dichloromethane as solvent and trimethylamine-N-oxide dihydrate as the reoxidant (Poli's conditions) gave levels of stereoselectivity that were superior to those found under more conventional oxidising conditions.
osmium tetroxide - acyclic stereocontrol - triols - catalyst - oxidation